Abstract
Mid-infrared absorption spectroscopy for gas detection is reported in this study using a quantum cascade laser (QCL) coupled with a custom-made tellurite hollow-core antiresonant fiber (HC-ARF). The HC-ARF is fabricated from tellurite glass by extrusion and subsequent fiber drawing. The QCL emitting at 5.26 µm is coupled into the 21-cm long HC-ARF. As a proof-of-concept, this spectroscopic system is demonstrated for nitric oxide (NO) detection by exploiting its strong absorption line at 1900.08 cm-1. By quickly filling gas mixtures into the HC-ARF, we first conduct direct absorption spectroscopy of NO and achieve a noise equivalent absorption (NEA) of 2.1 × 10-5 cm-1. Besides, we also conduct wavelength modulation spectroscopy to improve sensing performance. A minimum detection limit of 6 ppb NO is achieved at the integration time of 30 s, corresponding to 1.0 × 10-7 cm-1 in NEA. The HC-ARF is tested to show a response time of only 0.3 s when applying a pressure difference of 11 kPa between the two fiber ends. Such a tellurite HC-ARF-coupled QCL spectroscopic system makes it attractive for developing optical gas sensors with compact size, fast response, and high sensitivity.
PDF Article
More Like This
Extruded tellurite antiresonant hollow core fiber for Mid-IR operation
Andrea Ventura, Juliano Grigoleto Hayashi, Jaroslaw Cimek, Gregory Jasion, Petr Janicek, Fedia Ben Slimen, Nicholas White, Qiang Fu, Lin Xu, Hesham Sakr, Natalie V. Wheeler, David J. Richardson, and Francesco Poletti
Opt. Express 28(11) 16542-16553 (2020)
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription